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Linde HISORP

Linde is an industrial gas and engineering company with a global presence. They offer a wide range of industrial gases, engineering services, and equipment across various sectors like chemicals, energy, food & beverage, electronics, and healthcare. In recent years, Linde has emerged in the CCUS market with several technologies (OASE® blue and HISORP® CC).

They claim competitive advantage based on the following:

  1. Complete solutions providers: Linde provides an integrated business model by utilizing both their engineering and gas businesses. This allows them to provide Carbon Capture services across the value chain from capture and processing to conditioning, transportation, utilization, and storage.
  2. Technology agnostic: Linde is technology agnostic in their choice of capture technologies, based on the nature of the capture project. They offer OASE blue Amine-based capture technology and HISORP CC pressure-based adsorption capture technology. While HISORP is mainly considered for biogas plants with a lower CO2 content in flue gas, it can still be used for other applications (cement, waste-to-power, etc.)

Fact sheet

CO2 Capture rate

95% with CO2 inlet 8-95%

Capacity

>350kt+ CO2/year

Delivery time

NA

Footprint

Larger

Energy

High energy consumption,
Electricity only

Capture technolgy - Pressure Swing Adsorption

1.

1. Separation of liquids

In the first step of the Pressure Swing Adsorption, flue gas is compressed and treated through a separator (1.), where liquids are separated from the flue gas. This pre-treatment is key for operational optimization, allowing for even higher performance. 

1.2.2.

2. Adsorption of heavy hydrocarbons

During adsorption, the feed gas is routed from the top to the bottom of the respective adsorber in adsorption and the heavy hydrocarbons and water are adsorbed to produce an on-spec product. After a certain time, the adsorbent material is fully loaded and another adsorber switches HISORP® to adsorption mode. The fully loaded adsorber switches to the regeneration phase, which consists of the heating and cooling steps.

1.2.2.3.

3. Loaded adsorption material desorption

In the heating step, the regeneration gas is routed through the vessel from bottom to top at an elevated temperature. The previously
adsorbed impurities desorb and accumulate in the hot regeneration gas. The gas is subsequently cooled down and sent to a condensate
separator to separate the heavy hydrocarbons and water from the gaseous components.

Once the heating step has been completed, the adsorber vessel is cooled to adsorption temperature by using regeneration gas. This regeneration gas used for cooling is a split stream from the feed gas and it is routed through the vessel from top to bottom.

The gas leaving the adsorber vessel in the cooling step becomes the regeneration gas for the vessel in the heating step. In this way, heat losses are minimized, and heat is recovered efficiently.

After the separation of the condensable components, the regeneration gas is recycled from the condensate separator to the feed gas to maximize the recovery of valuable components. No compressor or blower is required for this process step. Instead, a throttle valve in the feed line compensates for the pressure loss of the regeneration gas to facilitate recycling. The entire process is designed for maximum efficiency.

Downstream treatment

The captured CO₂ can be further purified and liquefied for use in chemical or other industry processes. Alternatively, it can be purified to a food-grade level and used in the production of food and beverages.
Linde also specializes in CO₂ purification, liquefaction, storage and distribution technologies. The company offers a range of prefabricated, standardized solutions to accelerate deployment and maximize cost efficiencies.

Reference projects

While OASE® blue is a well-tested and deployed technology, HISORP® CC represents a newly developed solution in the Linde’s product offering with no integrations yet.